The three fundamental particles comprising most atoms are called protons, neutrons and electrons. Whilst the majority of atoms have a combination of protons, neutrons, and electrons, not all atoms have neutrons; an example is the protium isotope (1H1) of hydrogen (Hydrogen-1) which is the lightest and most common form of hydrogen which only has one proton and one electron. Atoms are far too small to be seen, but if we could look at one, it might appear something like this:
Even though each atom in a piece of material tends to hold together as a unit, there's actually a lot of empty space between the electrons and the cluster of protons and neutrons residing in the middle.
This crude model is that of the element carbon, with six protons, six neutrons, and six electrons. In any atom, the protons and neutrons are very tightly bound together, which is an important quality. The tightly-bound clump of protons and neutrons in the center of the atom is called the nucleus, and the number of protons in an atom's nucleus determines its elemental identity: change the number of protons in an atom's nucleus, and you change the type of atom that it is. In fact, if you could remove three protons from the nucleus of an atom of lead, you will have achieved the old alchemists' dream of producing an atom of gold! The tight binding of protons in the nucleus is responsible for the stable identity of chemical elements, and the failure of alchemists to achieve their dream.
Neutrons are much less influential on the chemical character and identity of an atom than protons, although they are just as hard to add to or remove from the nucleus, being so tightly bound. If neutrons are added or gained, the atom will still retain the same chemical identity, but its mass will change slightly and it may acquire strange nuclear properties such as radioactivity.
However, electrons have significantly more freedom to move around in an atom than either protons or neutrons. In fact, they can be knocked out of their respective positions (even leaving the atom entirely!) by far less energy than what it takes to dislodge particles in the nucleus. If this happens, the atom still retains its chemical identity, but an important imbalance occurs. Electrons and protons are unique in the fact that they are attracted to one another over a distance. It is this attraction over distance which causes the attraction between rubbed objects, where electrons are moved away from their original atoms to reside around atoms of another object.
Electrons tend to repel other electrons over a distance, as do protons with other protons. The only reason protons bind together in the nucleus of an atom is because of a much stronger force called the strong nuclear force which has effect only under very short distances. Because of this attraction/repulsion behavior between individual particles, electrons and protons are said to have opposite electric charges. That is, each electron has a negative charge, and each proton a positive charge. In equal numbers within an atom, they counteract each other's presence so that the net charge within the atom is zero. This is why the picture of a carbon atom had six electrons: to balance out the electric charge of the six protons in the nucleus. If electrons leave or extra electrons arrive, the atom's net electric charge will be imbalanced, leaving the atom "charged" as a whole, causing it to interact with charged particles and other charged atoms nearby. Neutrons are neither attracted to or repelled by electrons, protons, or even other neutrons, and are consequently categorized as having no charge at all.
The process of electrons arriving or leaving is exactly what happens when certain combinations of materials are rubbed together: electrons from the atoms of one material are forced by the rubbing to leave their respective atoms and transfer over to the atoms of the other material. In other words, electrons comprise the "fluid" hypothesized by Benjamin Franklin. The operational definition of a coulomb as the unit of electrical charge (in terms of force generated between point charges) was found to be equal to an excess or deficiency of about 6,250,000,000,000,000,000 electrons. Or, stated in reverse terms, one electron has a charge of about 0.00000000000000000016 coulombs. Being that one electron is the smallest known carrier of electric charge, this last figure of charge for the electron is defined as the elementary charge.
The result of an imbalance of this "fluid" (electrons) between objects is called static electricity. It is called "static" because the displaced electrons tend to remain stationary after being moved from one insulating material to another. In the case of wax and wool, it was determined through further experimentation that electrons in the wool actually transferred to the atoms in the wax, which is exactly opposite of Franklin's conjecture! In honor of Franklin's designation of the wax's charge being "negative" and the wool's charge being "positive," electrons are said to have a "negative" charging influence. Thus, an object whose atoms have received a surplus of electrons is said to be negatively charged, while an object whose atoms are lacking electrons is said to be positively charged, as confusing as these designations may seem. By the time the true nature of electric "fluid" was discovered, Franklin's nomenclature of electric charge was too well established to be easily changed, and so it remains to this day.
Michael Faraday proved (1832) that static electricity was the same as that produced by a battery or a generator. Static electricity is, for the most part, a nusiance. Black powder and smokeless powder have graphite added to prevent ignition due to static electricity. It causes damage to sensitive semiconductor circuitry. While is is possible to produce motors powered by high voltage and low current characteristic of static electricity, this is not economic. The few practical applications of static electricity include xerographic printing, the electrostatic air filter, and the high voltage Van de Graaff generator.